Switchable Surface Hydrophobicity-Hydrophilicity of a Metal-Organic Framework
نویسندگان
چکیده
منابع مشابه
An Electrically Switchable Metal-Organic Framework
Crystalline metal organic framework (MOF) materials containing interconnected porosity can be chemically modified to promote stimulus-driven (light, magnetic or electric fields) structural transformations that can be used in a number of devices. Innovative research strategies are now focused on understanding the role of chemical bond manipulation to reversibly alter the free volume in such stru...
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Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
متن کاملMetal-organic framework materials as nano photocatalyst
Photocatalytic degradation of toxic organic compound in water, soil and air by semiconductor catalysts such as TiO2 and ZnO have received much attention over the last two decades. However, the low quantum yield, easy agglomeration and difficult post-separation of these inorganic catalysts limit their application for large-scale applications. Metal-organic frameworks (MOFs) are the latest class ...
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A switchable-hydrophilicity solvent (SHS) is a solvent that in one state forms a biphasic mixture with water but can be reversibly switched to another state that is miscible with water. We describe a mathematical model of the behaviour of CO2-triggered SHS that narrows the search field for these solvents in terms of their basicity and hydrophilicity. By its predictive power, the mathematical mo...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2016
ISSN: 1433-7851
DOI: 10.1002/anie.201609295